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Supramolecular compounds of indium sulfates with nitrogen-containing cations

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Abstract

Compounds with a general formula [Cat][In(H2O) n (SO4)2] x · mH2O (where Cat = C(NH2)3, H(2,2′-Bipy), H2(4,4′-Bipy), H2[Py(CH2)3Py], and H3N(CH2)6NH3) were synthesized and identified from the elemental analysis, IR, and thermogravimetric analysis data. X-ray diffraction analysis of crystalline [C(NH2)3][In(H2O)2(SO4)2] complex showed that the polymer chains of In aquasulfate form ensembles with guanidinium ions. The structure of [H2(4,4′-Bipy)][In2(H2O)6(SO4)4] · 2H2O consists of the dimeric anions of indium sulfate. The coordination sphere of In includes three O atoms of three SO4 groups and three O atoms of water molecules. The dimers are united into framework by diprotonated Bipy cations.

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References

  1. Comprehensive Coordination Chemistry, Oxford: Pergamon, vol. 3, 1987.

  2. Petrosyants, S.P., Ilyukhin, A.B., and Sukhorukov, A.Yu., Koord. Khim., 2005, vol. 31, no. 8, p. 576.

    Google Scholar 

  3. Sheldrick, G.M., SHELXS97. Program for the Solution of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  4. Sheldrick, G.M., SHELXL97. Program for the Refinement of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  5. Ilyukhin, A.B. and Petrosyants, S.P., Zh. Neorg. Khim., 2004, vol. 49, no. 8, p. 1338 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 49, no. 8, p. 1232].

    CAS  Google Scholar 

  6. Mirĭeva, A. and Goliĭ, L., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1995, vol. 51, no. 2, p. 175.

    Article  Google Scholar 

  7. Ilyukhin, A. and Petrosyants, S.P., Private Commun., 2005, ICSD 391355.

  8. Ilyukhin, A. and Petrosyants, S.P., Private Commun., 2005, CCDC 293725.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    S. P. Petrosyants, A. B. Ilyukhin & V. A. Ketsko

Authors
  1. S. P. Petrosyants
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  2. A. B. Ilyukhin
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  3. V. A. Ketsko
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Additional information

Original Russian Text © S.P. Petrosyants, A.B. Ilyukhin, V.A. Ketsko, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 11, pp. 809–815.

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Petrosyants, S.P., Ilyukhin, A.B. & Ketsko, V.A. Supramolecular compounds of indium sulfates with nitrogen-containing cations. Russ J Coord Chem 32, 777–783 (2006). https://doi.org/10.1134/S1070328406110029

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  • DOI: https://doi.org/10.1134/S1070328406110029

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