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. 2005 Oct 26;127(42):14554-5.
doi: 10.1021/ja055066e.

instant "base-promoted" generation of roper's-type Ru(0) complexes Ru(CO)2(PR3)3 from a simple carbonylchlororuthenium(II) precursor

Stephane Sentets  1 , Maria del Carmen Rodriguez Martinez, Laure Vendier, Bruno Donnadieu, Vincent Huc, Noël Lugan, Guy Lavigne
Affiliations

instant "base-promoted" generation of roper's-type Ru(0) complexes Ru(CO)2(PR3)3 from a simple carbonylchlororuthenium(II) precursor

Stephane Sentets et al. J Am Chem Soc. .

Abstract

An uncommon synergism in the concerted action of OH- and PR3 toward the simple Ru(II) complex Ru(CO)3Cl2(thf) allows a highly efficient reduction of the metal in ethanol or acetonitrile solution at 0 degrees C, with selective production of the corresponding Roper's-type Ru(0) complexes Ru(CO)2(PR3)3 in high yields within 10 min.

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